Publication-2021


論文
7) Interdigitated Pt-Br chains with π-stacking: an approach toward Robin-Day class I mixed valency in MX-chain complexes
U. Afrin, K. Fuku, M. Cui, H. Iguchi, M. R. Mian, R. Nakanishi, S. Takaishi M. Yamashita
Dalton Trans., 2021, 50, 14215.
DOI: 10.1039/D1DT02996G


6) Reversible hydrogen adsorption at room temperature using a molybdenum?dihydrogen complex in the solid state
K. Uchida, N. Kishimoto, S. Noro, H. Iguchi, S. Takaishi
Dalton Trans., 2021, 50, 12630.
DOI: 10.1039/D1DT01404H


5) Surface Ohmic Conductivity on a Mott Insulator Based on a One-dimensional Bromide-bridged Nickel(III) Complex
M. Wakizaka, H. Iguchi, S. Takaishi, M. Yamashita
Chem. Asian J., 2021, 16, 2947.
DOI: 10.1002/asia.202100637


4) Ionic Charge-Transfer Liquid Crystals Formed by Alternating Supramolecular Copolymerization of Liquid π-Donors and TCNQ
H. Iguchi, H. Furutani, N. Kimizuka
Front. Chem., 2021, 9, 657246.
DOI: 10.3389/fchem.2021.657246


3) Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity
K. Kon, K. Uchida, K. Fuku, S. Yamanaka, B. Wu, D. Yamazui, H. Iguchi, H. Kobayashi, Y. Gambe, I. Honma, S. Takaishi
ACS Appl. Mater. Interfaces, 2021, 13, 38188.
DOI: 10.1021/acsami.1c06571
Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity



2) Bluish Hydrochromic Naphthalenediimide Salt: Change of Hydrogen-Bond Interactions as the New Mechanism of Vapochromism
T. Tanabe, T. Sato, K. Fuku, K. Uchida, T. Yamauchi, S. Takaishi, H. Iguchi
Chem. Lett., 2021, 50, 1479.
DOI: 10.1246/cl.210275
Bluish Hydrochromic Naphthalenediimide Salt: Change of Hydrogen-Bond Interactions as the New Mechanism of Vapochromism.



1) Unusual Pd(III) Oxidation State in Pd-Cl Chain Complex with Highly Thermal Stability and Electrical Conductivity
M. R. Mian, M. Wakizaka, T. Yoshida, H. Iguchi, S. Takaishi, U. Afrin, T. Miyamoto, H. Okamoto, H. Tanaka, S. Kuroda, B. K. Breedlove, M. Yamashita
Dalton Trans., 2021, 50, 1614-1619.
DOI: 10.1039/D0DT03848B
Unusual Pd(III) Oxidation State in Pd-Cl Chain Complex with Highly Thermal Stability and Electrical Conductivity'.

  多重水素結合を導入することにより、一次元Pd-Clナノワイヤー錯体として初めてPd(III)平均原子価状態の発現に成功しました。この錯体は2017年に報告したPd-Br錯体よりもさらに熱的に安定で、これまでで最も高温(470 K)までPd(III)状態を保持することが明らかとなりました。また、Pd-Cl-Pd距離が極めて短くなったことを反映して、室温電気伝導率も0.6 Scm-1と、Pd-Clナノワイヤー錯体として過去最高の値を示しました。

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