First observation of the (B)over-tilde(1)A(1) state of SiH2 and SiD2 radicals by optical-optical double resonance spectroscopy
Y. Muramoto, H. Ishikawa, N. Mikami,
J. Chem. Phys. 122, 154302 (2005).

The (B) over tilde (1)A(1) state of SiH2 and SiD2 was observed by the optical-optical double resonance technique for the first time. The electronic band origin of the (B) over tilde state of SiD2 was determined to be 27 214.11 cm-1. A very clear exclusive behavior depending on the even/odd value of the bending vibrational quantum number was observed in the spectra, representing a quasilinear behavior of the (B) over tilde state. The barrier height to linearity was estimated to be similar to 125 cm-1 by the quasilinear analysis of the bending vibrational level structure of SiD2.

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