Infrared spectra of jet-cooled tropolone-(H₂O)_n (n=1-3) and tropolone-(CH₃OH)_n (n=1 and 2) clusters were observed in the OH ctretching region by using infrared-ultraviolet double resonance techniques. Size separated electronic spectra of these clusters were also observed with hole-burning spectroscopy in which the infrared laser was used as hole light. Both the infrared and hole-burning spectra of the tropolone-methanol clusters were found to be quite similar to those of the corresponding tropolone-water clusters, indicating that a similar structure is expected for both the clusters. Structure of the n=1 and 2 clusters of tropolone-water and -methanol is discussed. The infrared (IR) spectra suggest that the intramolecular hydrogen bond of tropolone OH is not destroyed in tropolone-(H₂O)_n (n≤2) and -CH₃OH, while the intermolecular hydrogen bond dominates in tropolone-(H₂O)₃ and -(CH₃OH)₂. The transformation of the intramolecular to intermolecular hydrogen bond induced by the solvation is also discussed.